找回密码
 立即注册

QQ登录

只需一步,快速开始

查看: 796|回复: 1
打印 上一主题 下一主题

[专家学者] 扬州大学化学化工学院俞磊

[复制链接]

43

主题

43

帖子

51

积分

注册会员

Rank: 2

积分
51
跳转到指定楼层
楼主
发表于 2017-12-1 09:04:35 | 只看该作者 |只看大图 回帖奖励 |倒序浏览 |阅读模式
俞磊,1982年生于江苏泰州。2003年于南京大学获得学士学位,同年保送到浙江大学攻读博士学位,师从著名化学家黄宪院士,期间多次获得研究生一等奖学金、海正奖学金、三好研究生等奖励和荣誉。2008年毕业,获理学博士学位,并获得浙江大学优秀毕业研究生荣誉。同年来到扬州大学工作,在郭荣教授课题组从事博士后研究工作。2011年出站,并晋升副教授。2011年-2013年期间在江苏扬农化工集团有限公司从事企业博士后研究工作(流动站:南京大学;导师:潘毅教授、顾志强研究员)。2013年4月赴加拿大多伦多大学,在著名化学家、英国皇家协会会士Mark Lautens教授课题组访学,2014年4月回国。2015-2016年期间在南京大学范以宁教授课题组访问学习。2016年破格晋升教授、博导。
  俞磊博士课题组结合地方高校特点,进行务实的基础研究。主要方向为有工业应用前景的绿色化学研究。至今,已在Angew. Chem. Int. Ed., ACS Catal., Green Chem., J. Mater. Chem. A,Org. Lett., Chem. Commun., Adv. Synth. Catal., Catal. Sci. Technol., J. Org. Chem., ChemCatChem, Appl. Catal. A-Gen., Mol. Catal., Org. Biomol. Chem., Org. Process Res. Dev., Mater. Lett., RSC Adv., Mini-Rev. Med. Chem., Tetrahedron, Tetrahedron Lett., Synlett, Appl. Organometal. Chem., J. Organomet. Chem. 等SCI期刊上发表论文70余篇,获得授权发明专利8项。欢迎有学术志向的同学报考本课题组研究生。
  2012年以来代表作一览(更新日期:2017年8月17日)
(1) Tingting Wang, Xiaobi Jing, Chao Chen, Lei Yu,* Organoselenium-Catalyzed Oxidative C=C Bond Cleavage: A Relatively Green Oxidation of Alkenes into Carbonyl Compounds with Hydrogen Peroxide. J. Org. Chem. 2017, accepted, doi: 10.1021/acs.joc.7b01245. (SCI二区, 影响因子4.849)
http://pubs.acs.org/doi/10.1021/acs.joc.7b01245
(2) Yuguang Wang, Zhongli Wu, Qin Li, Bingchun Zhu,* Lei Yu,* Ruthenium-catalyzed oxidative decyanative cross-coupling of acetonitriles with amines in air: A general access of primary to tertiary amides under mild conditions. Catal. Sci. Technol. 2017, accepted, doi:10.1039/C7CY00761B. (SCI二区, 影响因子5.773)
http://pubs.rsc.org/en/content/articlelanding/2014/cy/c7cy00761b#!divAbstract
(3) Chi He, Zengbing Bai, Jialei Hu, Bingnan Wang, Hujun Xie,* Lei Yu,* Hanfeng Ding.* A Divergent [5+2] Cascade Approach to Bicyclo[3.2.1]octanes: Facile Synthesis ofent-Kaurene and Cedrene-Type Skeletons. Chem. Commun. 2017, 2017,53,8435-8438, DOI: 10.1039/C7CC04292B. (SCI一区, 影响因子6.319)
http://pubs.rsc.org/en/content/articlelanding/2017/cc/c7cc04292b#!divAbstract
(4) Duo Wei,* Mengting Han, Lei Yu,* Solid-State 77Se NMR of Organoselenium Compounds through Cross Polarization Magic Angle Spinning (CPMAS) Method. Sci. Rep., 2017, 7, 6376, DOI : 10.1038/s41598-017-06892-8 (SCI二区, 影响因子4.259)
https://www.nature.com/articles/s41598-017-06892-8
(5) Jun Xuan, Zhaobo Liu, An Zhu, Peirong Rao, Lei Yu, and Hanfeng Ding,* Diastereoselective Total Synthesis of Euphorbia Diterpenoid Pepluanol A: A Reductive Annulation Approach. Angew. Chem. Int. Ed., 2017, 56 (30), 8898-8901 doi: 10.1002/anie.201704929 (SCI一区, 影响因子11.994)
http://onlinelibrary.wiley.com/doi/10.1002/anie.201704929/abstract;jsessionid=43F14A659A55EF51D5062528348D2C97.f04t02
(6) Song Yao, Kaijing Zhou, Jiabing Wang, Hongen Cao, Lei Yu, Jianzhang Wu,* Peihong Qiu,* Qing Xu,* Synthesis of 2‐Subsitituted Quinazolines by CsOH‐Mediated Direct Aerobic Oxidative Cyclocondensation of 2‐Aminoaryl methanols with Nitriles in Air. Green Chem., 2017, 19, 2945-2951, DOI: 10.1039/C7GC00977A (SCI一区, 影响因子8.506)
http://pubs.rsc.org/en/content/articlelanding/2017/gc/c7gc00977a#!divAbstract
(7) Xiaobi Jing, Tingting Wang, Yuanhua Ding, Lei Yu*, A scalable production of anisonitrile through organoselenium-catalyzed dehydration of anisaldoxime under solventless conditions. Appl. Catal. A-Gen. 2017, 541, 107-111, doi: 10.1016/j.apcata.2017.05.007 (SCI二区, 影响因子 4.012)
http://www.sciencedirect.com/science/article/pii/S0926860X17301977
(8) Xiantao Ma, Lei Yu, Chenliang Su*, Yaqi Yang, Huan Li, Qing Xu*, Efficient Generation of C-S Bonds via a Byproduct-Promoted Selective Coupling of Alcohols, Organohalides, and Thiourea. Adv. Synth. Catal. 2017, 359(10), 1649-1655, doi: 10.1002/adsc.201700227 (SCI一区,影响因子6.45)
(9) Xiaobi Jing, Dandan Yuan, Lei Yu*, Green and Practical Oxidative Deoximation of Oximes to Ketones or Aldehydes with Hydrogen Peroxide/Air by Organoselenium Catalysis. Adv. Synth. Catal. 2017, 359(7), 1194-1201, doi: 10.1002/adsc.201601353 (SCI一区,影响因子6.453)
http://dx.doi.org/10.1002/adsc.201601353
(10) Fang Wang, Lin Xu, Jiejun Huang, Shishi Wu, Lei Yu*, Qing Xu* and Yining Fan*, Practical preparation of methyl isobutyl ketone by stepwise isopropylation reaction of acetone, Mol. Catal.(Former J. Mol. Catal. A-Chem.), 2017, 432C, 99-103, doi: 10.1016/j.mcat.2017.02.010. (Editor’s Choice Paper, 影响因子3.958)
(11) Fenglin Chen, Yao Zhang, Lei Yu and Shaolin Zhu*, Enantioselective NiH/Pmrox-Catalyzed 1,2-Reduction of α,β-Unsaturated Ketones. Angew. Chem. Int. Ed. 2017, 56(8), 2022-2025.10.1002/anie.201610990 (SCI一区,影响因子11.709)
http://onlinelibrary.wiley.com/doi/10.1002/anie.201610990/full
(12) Shengcai Deng, Tingting Meng, Bolian Xu, Fei Gao, Yuanhua Ding, Lei Yu* and Yining Fan,* Advanced MnOx/TiO2 Catalyst with Preferentially Exposed Anatase {001} Facet for Low-temperature SCR of NO. ACS Catal., 2016, 6, 5807-5815. (SCI一区,影响因子9.307)
http://pubs.acs.org/doi/abs/10.1021/acscatal.6b01121
(13) Yuguang Wang, Lihua Yu, Bingchun Zhu,* and Lei Yu,* Design and preparation of polymer resin-supported organoselenium catalyst with industrial potential, J. Mater. Chem. A, 2016, 4(28), 10828-10833 (SCI一区,影响因子8.262)
http://pubs.rsc.org/en/content/articlelanding/2016/ta/c6ta02566h#!divAbstract
(14) Lei Yu,* Fenglin Chen and Yuanhua Ding, Organoselenium-Catalyzed Oxidative Ring Expansion of Methylenecyclopropanes with Hydrogen Peroxide. ChemCatChem, 2016, 2016, 8(6), 1033-1037 (影响因子4.556, 封面文章)
http://onlinelibrary.wiley.com/doi/10.1002/cctc.201501309/full
(15) Lei Yu,* ZengbingBai, Xu Zhang, Xiaohong Zhang, Yuanhua Ding and Qing Xu, Organoselenium-Catalyzed Selectivity-Switchable Oxidation of β-Ionone. Catal. Sci. Technol., 2016, 6, 1804-1809 (影响因子5.426)
http://pubs.rsc.org/en/content/articlelanding/2014/cy/c5cy01395j
(16) Shengcai Deng, KeZhuang, BolianXu, Yuanhua Ding, Lei Yu* and Yining Fan,* Promotional effect of iron oxide on the catalytic properties of Fe-MnOx/TiO2 (Anatase) Catalysts for the SCR reaction at low temperatures. Catal. Sci. Technol., 2016, 6, 1772-1778 (影响因子5.426)
http://pubs.rsc.org/en/content/articlelanding/2014/cy/c5cy01217a
(17) Lei Yu,* Mengting Han, Jie Luan, Lin Xu, Yuanhua Ding and Qing Xu, Ca(OH)2-Catalyzed Condensation of Aldehydes with Methyl ketones in Dilute Aqueous Ethanol: A Comprehensive Access to α,β-Unsaturated Ketones. Sci. Rep., 2016, 6, 30432; doi: 10.1038/srep30432. (影响因子5.228).
http://www.nature.com/articles/srep30432
(18) Hualan Zhou, Jingjing Gong, Bolian Xu, Lei Yu* and Yining Fan,* PtSnNa@SUZ-4-catalyzedpropane dehydrogenation. Applied Catalysis A: General, 2016, 527, 30-35. (影响因子4.012)
http://www.sciencedirect.com/science/article/pii/S0926860X16304240
(19) Lei Yu*, Zhe Han and Yuanhua Ding, Gram-Scale Preparation of Pd@PANI: A Practical Catalyst Reagent for Copper-Free and Ligand-Free Sonogashira Couplings. Org. Process Res. Dev. 2016, ASAP, DOI: 10.1021/acs.oprd.6b00322 (影响因子2.922)
(20) Qing Tong, Anyi Zong, Wei Gong, Lei Yu* and Yining Fan,* Rhenium-promoted Pt/WO3/ZrO2: An efficient catalyst for aqueous glycerol hydrogenolysis under reduced H2 pressure. RSC Adv., 2016, 6, 86663 - 86672. (影响因子3.289)
http://pubs.acs.org/doi/abs/10.1021/acs.oprd.6b00322
(21) Lei Yu* and Zhe Han, Palladium nanoparticles on polyaniline (Pd@PANI): A practical catalyst for Suzuki cross-couplings. Mater. Lett., 2016, 184, 312-314. (影响因子2.437).
http://www.sciencedirect.com/science/article/pii/S0167577X16313349
(22) Xu Zhang, Jingjing Sun, Yuanhua Ding and Lei Yu,* Dehydration of Aldoximes Using PhSe(O)OH as the Pre-Catalyst in Air. Org. Lett., 2015, 17, asap, doi: 10.1021/acs.orglett.5b03011.( SCI一区,影响因子6.364)
http://pubs.acs.org/doi/abs/10.1021/acs.orglett.5b03011
http://pubs.rsc.org/en/content/articlelanding/2014/cy/c5cy01217a
(23) Lei Yu,* Yaping Huang, Zheng Wei, Yuanhua Ding, Chenliang Su* and Qing Xu,* Heck Reactions Catalyzed by Ultrasmall and Uniform Pd Nanoparticles Supported on Polyaniline. J. Org. Chem., 2015, 80, 8677-8683. (影响因子4.721)
http://pubs.acs.org/doi/abs/10.1021/acs.joc.5b01358
(24) Lei Yu,* Jianqing Ye, Xu Zhang, Yuanhua Ding and Qing Xu,* Recyclable (PhSe)2-Catalyzed Selective Oxidation of Isatin by H2O2: A Practical and Waste-Free Access to Isatoic Anhydride under Mild and Neutral Conditions. Catal. Sci. Technol. 2015, 5, 4830-4838 (影响因子5.426)
http://pubs.rsc.org/en/content/articlelanding/2014/cy/c5cy01030f
(25) Lei Yu,* Mingxuan Liu, Fenglin Chen and Qing Xu*, Heterocycles from Methylenecyclopropanes, Org. Biomol. Chem. 2015, 13, 8379-8392.(影响因子3.562)
http://pubs.rsc.org/en/content/articlelanding/2014/ob/c5ob00868a
外封面论文
(26) Xu Zhang, Jianqing Ye, Lei Yu,* Xinkang Shi, Ming Zhang, Qing Xu*, Mark Lautens. Recyclable Organoselenium-Catalyzed Baeyer-Villiger Oxidation of α,β-Unsaturated Ketones by H2O2: A Green Access to Vinyl Esters. Adv. Synth. Catal. 2015, 357, 955-960. (SCI一区,影响因子5.663)
http://onlinelibrary.wiley.com/doi/10.1002/adsc.201400957/abstract
Highlighted by X-MOL化学资讯平台 http://x-mol.com/news/470
(27) Lin Xu, Jiejun Huang, Yubing Liu, Yining Wang, BolianXu, Kehong Ding, Yuanhua Ding, Qing Xu, Lei Yu* and Yining Fan,* Design and Application of the Recyclable Poly (L-Proline-co-Piperidine) Catalyst for the Synthesis of Mesityl Oxide from Acetone. RSC Adv. 2015, 5, 42178-42185. (影响因子3.84)
http://pubs.rsc.org/en/content/articlelanding/2014/ra/c5ra05741h#!divAbstract
(28) Kai Zhang, Hang Wang, JingfengZheng, Lei Yu, Hanfeng Ding,* Hypervalent iodine mediated alkene difunctionalization of vinylphenols: diastereoselective synthesis of substituted indoles and indolizines. Chem. Commun. 2015, 51, 6399-6402. (SCI一区,影响因子6.834)
http://pubs.rsc.org/en/content/articlelanding/2015/cc/c5cc00441a
(29) Qing Xu*, HuameiXie, Pingliang Chen, Lei Yu, Jianhui Chen and Xingen Hu,* Organohalides-Catalyzed Dehydrative O-Alkylation between Alcohols: A Facile Etherification Method for Aliphatic Ether Synthesis. Green Chem. 2015, 17, 2774-2779. (SCI一区,影响因子8.02)
http://pubs.rsc.org/en/content/articlelanding/2014/GC/C5GC00284B#!divAbstract
(30) Lei Yu,* Hongyan Li, Xu Zhang, Jianqing Ye, Jianping Liu, Qing Xu* and Mark Lautens, Organoselenium-Catalyzed Mild Dehydration of Aldoximes: An Unexpected Practical Method for Organonitrile Synthesis.Org. Lett. 2014, 16, 1346-1349. (SCI一区,影响因子6.364)
http://pubs.acs.org/doi/abs/10.1021/ol500075h
(31) Lei Yu,* Yulan Wu, Hongen Cao, Xu Zhang, Xinkang Shi, Jie Luan, Tian Chen, Yi Pan and Qing Xu,*Facile Synthesis of 2-Methylenecyclobutanones via Ca(OH)2- Catalyzed Direct Condensation of Cyclobutanone with Aldehydes and (PhSe)2-Catalyzed Baeyer-Villiger Oxidation to 4-Methylenebutanolides. Green Chem. 2014, 16, 287-293. (SCI一区,影响因子8.02)
http://pubs.rsc.org/en/content/articlelanding/2013/gc/c3gc41562g#!divAbstract
(32) Yuguang Wang, Bingchun Zhu, Qing Xu, Qing Zhu*, and Lei Yu,* Synthesis of Heterocycle-Tethered Acylbenzofurans and Benzodifurans from Odorless and Recyclable Organoseleno Polystyrene Resin. RSCAdv. 2014,4, 49170-49179. (影响因子3.84)
http://pubs.rsc.org/en/content/articlelanding/2014/ra/c4ra08441a
(33) Xiaojuan Jia[+], Lei Yu[+], Jianping Liu, Qing Xu*,Marcel Sickert,Lianhui Chen and Mark Lautens,* Sulfur-silicon bond activation catalysed by Cl/Br ions: waste-free synthesis of unsymmetrical thioethers by replacing fluoride catalysis and fluorinated substrates in SNAr reactions. Green Chem. 2014, 16, 3444-3449. (SCI一区,影响因子8.02) ([+] These authors contributed equally to this work.)
http://pubs.rsc.org/en/content/articlelanding/2014/gc/c4gc00535j#!divAbstract
(34) Haonan Chen, WujieDai, Yi Chen, Qing Xu*, JianhuiChen, Lei Yu, Yajuan Zhao, Mingde Ye andYuanjiang Pan,* Efficient and selective nitrile hydration reaction in water catalyzed by unexpected dimethylsulfinyl anion generated in situ from CsOH and DMSO. Green Chem. 2014, 16, 2136 - 2141. (SCI一区,影响因子8.02)
http://pubs.rsc.org/en/content/articlelanding/2013/gc/c3gc42310g#!divAbstract
(35) Lei Yu,* Jun Wang, Xu Zhang, Hongen Cao, Genlin Wang, Kehong Ding, Qing Xu* and Mark Lautens, Practical and scalable preparation of 2-methyleneglutaronitrile via an efficient and highly selective head-to-tail dimerization of acrylonitrile catalysed by low-loading tricyclohexylphosphine. RSC Adv. 2014, 4,19122-19126. (影响因子3.84)
http://pubs.rsc.org/en/content/articlelanding/2014/ra/c4ra02810d#!divAbstract
(36) Lei Yu,* Yulan Wu,Tian Chen,Yi Pan,Qing Xu,* Direct Synthesis of Methylene-1,2-dichalcogenolanes via Radical [3+2] Cycloaddition of Methylenecyclopropanes with Elemental Chalcogens. Org. Lett. 2013,15, 144-147. (SCI一区,影响因子6.364)
http://pubs.acs.org/doi/abs/10.1021/ol3031846
(37) Lei Fan,Rong Yi, Lei Yu,* Yulan Wu,TianChen, RongGuo, Pd @ Aluminum Foil: A Highly Efficient and Environment-Friendly “Tea Bag” Style Catalyst with High TON. Catal. Sci. Technol. 2012, 2, 1136-1139. (影响因子5.426)
http://pubs.rsc.org/en/content/articlelanding/2012/cy/c2cy20132a
联系方式:email: yulei@yzu.edu.cn
有关本课题组更多信息,请参考课题组在科学网的网页:
http://blog.sciencenet.cn/u/YuLei82

  声明:本网部分文章和图片来源于网络,发布的文章仅用于材料专业知识和市场资讯的交流与分享,不用于任何商业目的。任何个人或组织若对文章版权或其内容的真实性、准确性存有疑义,请第一时间联系我们,我们将及时进行处理。
分享到:  QQ好友和群QQ好友和群 QQ空间QQ空间 腾讯微博腾讯微博 腾讯朋友腾讯朋友
收藏收藏 转播转播 分享分享 分享淘帖
回复

使用道具 举报

76

主题

93

帖子

97

积分

注册会员

Rank: 2

积分
97
沙发
发表于 2018-4-23 11:15:23 | 只看该作者
环己烯可控选择性催化氧化的最新进展
曹洪恩a, 朱柏燃a, 杨钰帆a, 徐林a,b, 俞磊a, 徐清a
a 扬州大学化学化工学院及园艺与植物保护学院农药研究所, 江苏扬州 225009;
b 江苏扬农化工集团有限公司, 江苏扬州 225009

摘要
环己烯是一种价格低廉易得的大宗化工原料,通常由苯选择性加氢来合成.该化合物虽然分子结构简单,但却有两个不同的反应位点.随着反应所发生的位点与反应深度的不同,环己烯的氧化反应可生成一系列不同氧化程度与官能团的产物的混合物.环己烯双键的氧化反应,可生成环氧环己烷,而环氧环己烷进一步水解,则生成1,2-环己二醇,其中,随着使用不同催化剂导致的反应机理差异,产物可分别为顺式或反式结构.在强氧化剂作用下,环己烯双键充分氧化,可生成己二酸.环己烯烯丙基C-H键氧化,则可随着反应深度的不同分别生成2-环己烯醇与2-环己烯酮.
上述环己烯氧化产物都是重要的有机化工中间体.其中,环氧环己烷是农药杀螨剂的主要原料,也用作合成表面活性剂、橡胶助剂等有用产品;1,2-环己二醇可用于合成化工中间体邻苯二酚;环己烯醇与环己烯酮是生产除草剂、香水、药物的原料;己二酸则是合成重要产品尼龙-6,6的原料.因此,随着市场需求的变化,对环己烯氧化反应进行选择性控制,提高其中某种产物的选择性,是重要的化工合成技术,有着巨大的应用潜力;从而控制反应历程与深度是有机化工合成工艺研究中最具有挑战性的研究课题之一,有很好的科学意义.
目前,人们对环己烯的选择性控制氧化反应已进行了广泛的研究.该反应可使用金属催化剂,包括铁、钴、镍、锰、铬、钒、钨、铜、钛、金、银、铋、锇、钼、镉等;也可以使用无金属催化剂如磺酸、2,2,2-三氟苯乙酮、类石墨相碳化氮(g-C3N4)等.反应可使用化学氧化剂,如间氯过氧苯甲酸、醋酸碘苯、过氧叔丁醇等,也可使用更加清洁的过氧化氢、分子氧.研究表明,催化剂的种类、用量,以及反应溶剂、温度、氧化剂等一系列外在条件,可以影响环己烯氧化反应的选择性.本文以反应所使用的氧化剂归类,总结了该课题的最新研究进展,以期对从事环己烯可控选择性氧化的学术与工业研究人员有所帮助.
国家自然科学基金(21202141,21672163);江苏省高校优势学科项目.
通讯作者: 俞磊, 徐清     E-mail: yulei@yzu.edu.cn;xuqing@yzu.edu.cn


回复 支持 反对

使用道具 举报

小黑屋|手机版|Archiver|版权声明|一起进步网 ( 京ICP备14007691号-1

GMT+8, 2024-5-20 17:50 , Processed in 0.088288 second(s), 34 queries .

Powered by Discuz! X3.2

© 2001-2013 Comsenz Inc.

快速回复 返回顶部 返回列表