浙江大学化学工程与生物工程学院工业生态与环境研究所杨启炜

chengzhi

杨启炜      博士
硕士生导师，副研究员   
联系方式
办公室：浙江大学玉泉校区教四320
电话/传真：0571-87951225
E-mail: yangqw@zju.edu.cn
研究兴趣
离子材料设计与应用
化工分离技术
量子化学与分子模拟
天然活性物质分离纯化
荣誉奖励
侯德榜化工科学技术奖青年奖（2017）
离子液体与绿色过程青年创新奖（2017）
浙江省科学技术进步一等奖（2014）
中国博士后基金特别资助（2012）
教育科研经历
浙江大学化工系，生物工程，本科，2001.9-2005.7
浙江大学化工系，应用化学，博士，2005.9-2010.9
浙江大学化工系，博士后，2010.10-2013.2
浙江大学化工系，助理研究员，2013.3-2013.12
浙江大学化工系，副研究员，2014.1-至今
美国麻省理工学院，访问学者，2017.8-至今
承担项目
国家重点研发计划项目课题
国家自然科学基金重点项目子课题
国家自然科学基金项目
浙江省自然科学基金项目
浙江省重点科技团队项目
中央高校基本科研项目
代表性论文
      在Science, Adv. Mater., Angew. Chemie. Int. Ed., AIChE J., Green Chem., Chem. Commun., Chem. Eng. J.等权威期刊上发表SCI论文60余篇，多篇论文获得”ESI高被引论文“、“Top Cited Papers"、封面/后封面论文等荣誉：
2017
1、Yuhui Li, Mohammad Chand Ali, Qiwei Yang*, Zhiguo Zhang, Zongbi Bao, Baogen Su, Huabin Xing, Qilong Ren. Hybrid deep eutectic solvents with flexible hydrogen-bonded supramolecular networks for highly efficient uptake of NH3. ChemSusChem 2017, 10, 3368-3377 (Front cover & Cover profile)
2、Zhaoqiang Zhang#, Qiwei Yang#, Xili Cui, Lifeng Yang, Zongbi Bao, Qilong Ren, Huabin Xing*. Sorting of c4 olefins with interpenetrated hybrid ultramicroporous materials by combining molecular recognition and Size-Sieving. Angew. Chem. Int. Ed. 2017, 56, 16282-16287 (Inside Front Cover & VIP Paper)
3、Xili Cui, Qiwei Yang*, Lifeng Yang, Rajamani Krishna, Zhiguo Zhang, Zongbi Bao, Hui Wu, Qilong Ren, Wei Zhou, Banglin Chen*, Huabin Xing*. Ultrahigh and selective SO2 uptake in inorganic anion-pillared hybrid porous materials. Adv. Mater. 2017, 29, 1606929 (Featured as Frontispiece)
4、Xili Cui, Qiwei Yang*, Yijun Xiong, Zongbi Bao, Huabin Xing* and Sheng Dai. Preparation of ordered N-doped mesoporous carbon materials via a polymer–ionic liquid assembly. Chem. Commun. 2017, 53, 4915-4918(Back Cover)
5、Jie Ma, Ming Zhang, Baogen Su, Yiwen Yang, Qiwei Yang* and Qilong Ren, Numerical simulation of the entrained flow hydropyrolysis of coal in magnetically rotating plasma reactor, Energy Convers. Manage. 2017, 431-439
6、Xianxian liu, Cai Ji, Qiwei Yang*, Zongbi Bao, Xiaohui Fan, Yiwen Yang* and Huabin Xing. Carboxylate Ionic Liquids Combining Low Cytotoxicity toward HepG2 Cell and High Separation Efficiency for Bioactive Molecules. ACS Sustainable Chem. Eng., 2017, 5 (2): 1974–1981
7、Wenbin Jin, Yuqi Ke, Xianxian Liu, Qiwei Yang*, Zongbi Bao, Baogen Su, Qilong Ren, Yiwen Yang and Huabin Xing. Enhanced self-assembly for the solubilization of cholesterol in molecular solvent/ionic liquid mixtures. Phys. Chem. Chem. Phys. 2017, 19,10835-10842 (Back Cover)
8、Ming Zhang, Jie Ma, Baogen Su, Guangdong Wen, Qiwei Yang * and Qilong Ren. Pyrolysis of polyolefins using rotating arc plasma technology for production of acetylene. Energies 2017, 10, 513-525.
9、Xian Suo, Ling Xia, Qiwei Yang, Zhiguo Zhang, Zongbi Bao, Qilong Ren, Yiwen Yang, Huabin Xing. Synthesis of anion-functionalized mesoporous poly(ionic liquid)s via a microphase separation-hypercrosslinking strategy: Highly efficient adsorbents for bioactive molecules. J.Mater. Chem. A 2017, 5, 14114-14123.
2016
1、Xili Cui#, Kaijie Chen#, Huabin Xing*, Qiwei Yang, Rajamani Krishna, Zongbi Bao, Hui Wu, Wei Zhou, Xinglong Dong, Yu Han, Bin Li, Qilong Ren, Michael J. Zaworotko*, Banglin Chen *. Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene. Science, 2016, 353(6295)：141~144

2、M. C. Ali, Qiwei Yang,* A. A. Fine, Wenbin Jin, Zhiguo Zhang, Huabin Xing and Qilong Ren,* Efficient removal of both basic and non-basic nitrogen compounds from fuels by deep eutectic solvents, Green Chem. 2016, 18, 157–164. (back cover)
3、Qiwei Yang#, Zhiping Wang#, Zongbi Bao, Zhiguo Zhang, Yiwen Yang，Qilong Ren，Huabin Xing*, Sheng Dai. New insights into CO2 absorption mechanisms with amino-acid ionic liquids. ChemSusChem, 2016, 9: 806~812 (Front Cover & Cover Profile)
2015及以前
1、Qiwei Yang, Dan Xu, Jingzhu Zhang, Yaoming Zhu, Zhiguo Zhang, Chao Qian, Qilong Ren, Huabin Xing*. Long-chain fatty acid–based phosphonium ionic liquids with strong hydrogen-bond basicity and good lipophilicity: Synthesis, characterization and application in extraction, ACS Sustain. Chem. Eng., 2015, 3(2): 309−316 (Cover Story)


2、Qiwei Yang, Huabin Xing*, Baogen Su, Zongbi Bao, Jun Wang, Yiwen Yang, Qilong Ren*. The essential role of hydrogen-bonding interaction in the extractive separation of phenolic compounds by ionic liquid. AIChE J. 2013, 59(5): 1657-1667. (ZJU100)
3、Qiwei Yang, Huabin Xing*, Baogen Su, Kun Yu, Zongbi Bao, Yiwen Yang, Qilong Ren*. Improved separation efficiency using ionic liquid-cosolvent mixtures as the extractant in liquid-liquid extraction: a multiple adjustment and synergistic effect. Chem .Eng. J. 2012, 181-182, 334-342.
4、Qiwei Yang, Huabin Xing*, Zongbi Bao, Baogen Su, Zhiguo Zhang, Yiwen Yang, Sheng Dai, Qilong Ren*. One of the Distinctive Properties of Ionic Liquids over Molecular Solvents and Inorganic Salts: Enhanced Basicity Stemming from the Electrostatic Environment and “Free” Microstructure. J. Phys. Chem. B. 2014, 118(13): 3682-3688(Chemical Engineering Journal Most Cited Paper for 2011 and 2012)
5、Dan Xu, Qiwei Yang, Baogen Su, Zongbi Bao, Qilong Ren, Huabin Xing*.  Enhancing the basicity of ionic liquids by tuning the cation-anion interaction strength and via the anion-tethered strategy. J. Phys. Chem. B, 2014, 118(4), 1071-1079. (ZJU-TOP期刊)
6、Qiwei Yang, Kun Yu, Huabin Xing*, Baogen Su, Zongbi Bao, Yiwen Yang, Qilong Ren. The effect of molecular solvents on the viscosity, conductivity and ionicity of mixtures containing chloride anion-based ionic liquid. J. Ind. Eng. Chem., 2013, 19 (5), 1708-1714.
7、Liyun Kong, Qiwei Yang, Huabin Xing*, Baogen Su, Zongbi Bao, Zhiguo Zhang, Yiwen Yang, Qilong Ren. A general method for the separation of amphiphilic surface-active poly (ethylene glycol) mono-and di-esters with long-chain ionic liquid-based biphasic systems, Green Chem.2014, 16, 102-107
8、Huabin Xing, Xiao Zhang, Qiwei Yang, Ruiyang Liu, Baogen Su, Yiwen Yang*, Qilong Ren. Separation of Long Chain Fatty Acids with Different Number of Unsaturated Bonds by Fractional Extraction: Experimental and COSMO-RS Study. Food. Chem., 2014, 143, 411. (ZJU100期刊)
9、Qiwei Yang, Huabin Xing*, Yifeng Cao, Baogen Su, Yiwen Yang, Qilong Ren. Selective separation of tocopherol homologues by liquid-liquid extraction using ionic liquids. Ind. Eng. Chem. Res. 2009, 48(13), 6417-6422 (ZJU-TOP期刊)
10、Qiwei Yang, Zuojun Wei, Huabin Xing, Qilong Ren*. . Brönsted acidic ionic liquids as novel catalysts for the hydrolyzation of soybean isoflavone glycosides. Catal. Commun. 2008, 9, 1307-1311.
11、Huabin Xing, Yan Yan, Qiwei Yang, Zongbi Bao, Baogen Su, Yiwen Yang, Qilong Ren*. . Effect of Tethering Strategies on the Surface Structure of Amine-Functionalized Ionic Liquids: Inspiration on the CO2 Capture. J. Phys. Chem. C, 2013,117 (31), 16012-16021.
12、Yifeng Cao, Huabin Xing*, Qiwei Yang, Zongbi Bao, Baogen Su, Yiwen Yang, Qilong Ren*.  Separation of soybean isoflavone aglycone homologues by ionic liquid-based extraction. J. Agric. Food. Chem. 2012, 60, 3432−3440
13、Xiaolei Ni, Huabin Xing*, Qiwei Yang, Jun Wang, Baogen Su, Zongbi Bao, Yiwen Yang, Qilong Ren. Selective liquid−liquid extraction of natural phenolic compounds using amino acid ionic liquids: a case of α-tocopherol and methyl linoleate separation. Ind. Eng. Chem. Res. 2012, 51, 6480−6488.  
14、 Huabin Xing*, Xu Zhao, Qiwei Yang, Baogen Su, Zongbi Bao, Yiwen Yang, Qilong Ren. Molecular Dynamics Simulation Study on the Absorption of Ethylene and Acetylene in Ionic Liquids. Ind. Eng. Chem. Res., 2013, 52 (26), 9308-9316.
15、Rulong Li, Huabin Xing*, Qiwei Yang, Xu Zhao, Baogen Su, Zongbi Bao, Yiwen Yang, Qilong Ren. Selective extraction of 1-hexene against n-hexane in ionic liquids with or without silver salt.Ind. Eng. Chem. Res., 2012. 51 (25), 8588–8597 (ZJU-TOP期刊)
16、Xu Zhao, Huabin Xing*, Qiwei Yang, Rulong Li, Baogen Su, Zongbi Bao, Yiwen Yang, Qilong Ren*.Differential Solubility of Ethylene and Acetylene in Room Temperature Ionic Liquids: A Theoretical Study. J Phys. Chem. B, 2012, 116, 3944–3953.
17、Yifeng Cao, Huabin Xing*, Qiwei Yang, Baogen Su, Zongbi Bao, Ruihan Zhang, Yiwen Yang, Qilong Ren. L.High performance separation of sparingly aqua-/lipo-soluble bioactive compounds with a ionic liquid-based biphasic system. Green Chem. 2012, 14, 2617.
18、Qilong Ren, Huabin Xing, Zongbi Bao, Baogen Su, Qiwei Yang, Yiwen Yang, Zhiguo Zhang. Progress in bioactive natural product separation. Chinese J. Chem. Eng., 2013, 21, 937-952 (Invited review)
19、Qianqian Xu, Baogen Su*, Xinyi Luo, Huabin Xing, Zongbi Bao, Qiwei Yang, Yiwen Yang, Qilong Ren*.  Accurate Measurements of Infinite Dilution Activity Coefficients Using Gas Chromatography with Static-Wall-Coated Open-Tubular Columns. Anal. Chem., 2012, 84, 9109(ZJU-TOP期刊)
发明专利
  申请中国发明专利八十余项，授权35项。代表性专利如下：
o 杨启炜，M.C. 阿里，邢华斌，鲍宗必，张治国，苏宝根，任其龙，一种无氮低共熔溶剂萃取脱除油品中碱性氮化物的方法，2015101423987
o 杨启炜，M.C. 阿里，张治国，鲍宗必，苏宝根，邢华斌，任其龙，一种低共熔溶剂萃取脱除油品中含氮化合物的方法，2015101414507
o 杨启炜，邢华斌，鲍宗必，苏宝根，张治国，任其龙等，一种采用离子液体萃取分离纯化磷脂酰胆碱的方法，201310170809.4
o 任其龙，杨启炜，邢华斌，苏宝根，杨亦文，曹义风，倪晓蕾，一种从混合生育酚中分离D-α -生育酚的方法，200810163013.5
o 邢华斌，曹义风，杨启炜，苏宝根，杨亦文，苏云等，一种从银杏内酯混合物中分离银杏内酯B的方法，201010608847.X
o 邢华斌, 倪晓蕾, 杨启炜, 曹义风, 苏宝根, 鲍宗必等，一种从植物油脱臭馏出物中分离混合生育酚的方法，201010584105.8
o 任其龙，曹义风，邢华斌，杨启炜，杨亦文，苏宝根等，从大豆异黄酮苷元混合物中分离染料木素的方法，201010114937.3
o 邢华斌，曹义风，任其龙，杨启炜，苏宝根，鲍宗必等，一种从辣椒碱类化合物中分离辣椒碱单体的方法，201210065573.3
学术编著
1、Ren Q.L., Yang Q.W., Su B.G., Zhang Z.G., Xing H.B., Bao Z.B. Ionic Liquid-Based Nonaqueous Microemulsion. Wiley, Inc. 2015
2、Ren Q.L., Yang Q.W., Yan Y., Xing H.B., Bao Z.B., Su B.G., Yang Y.W. Ionic liquid-mediated liquid-liquid extraction. Applications of Ionic Liquids in Science and Technology. InTech Press, Rijeka, Croatia, 2011

jianeite

Chem. Soc. Rev.综述：离子液体及其衍生材料在锂、钠电池领域的研究进展

随着新能源技术和智能设备在全球范围内的高速发展，锂电池和钠电池的创新研究已成为当前科技领域最引人瞩目的焦点之一。不断突破锂、钠电池电化学性能和安全性要求的关键在于设计开发更先进的电极、电解质及辅助材料。离子液体是完全由阴、阳离子组成的新型液体软材料，具有几乎不挥发、离子电导率高、热稳定性好、不易燃、电化学窗口宽等独特性质，不仅为能量/功率密度更高、长周期稳定性和安全性更好的新型电池材料的设计创造了新的机遇，也为已知材料制备方法的革新提供了新的可能。聚离子液体、离子凝胶和离子液体键合纳米颗粒等离子液体衍生材料在保留离子液体多数特性的同时被赋予了其它优良性能，因而也受到了极大关注。近十年来，涉及离子液体及其衍生材料在锂、钠电池领域研究的论文数量始终保持快速增长的趋势。

近日，浙江大学杨启炜副研究员、邢华斌教授和美国橡树岭国家实验室的Sheng Dai教授团队合作，在Chemical Society Reviews 上发表了题为《Ionic liquids and derived materials for lithium and sodium batteries》的专题综述论文，系统总结了离子液体及其衍生材料在锂/钠离子电池、双离子电池、锂/钠-硫电池、锂/钠-空电池等锂、钠电池中的各种应用，涵盖电极材料制备、液体电解质、固体电解质、电极/电解质界面与集流体等等不同用途，重点介绍了最近三年的研究进展。从技术角度而言，得益于其不同于分子溶剂和无机盐的独特性质，离子液体及其衍生材料是锂、钠电池制造过程中富有潜力的碳原子/杂原子前体、溶剂、添加剂或离子传导材料，不仅极大提升了电池的安全性，而且显著增强了电池的电化学性能及其制造过程的可持续性。但是目前仍有一些问题有待解决。例如，只有一部分离子液体在裂解时可以提供较高的碳收率与氮含量，而这些离子液体的合成步骤普遍较多，成本较高。在离子液体辅助的电极材料离子热合成过程中，离子液体与合成前体及中间产物的相互作用规律未被充分揭示，导致对产物结构的预测能力较弱。用作电解质时，离子液体较大的粘度限制了离子的传输，尤其是低温条件下的传输，同时一些离子液体及其衍生材料在苛刻条件下的长周期稳定性并没有通常认为的那样理想。从经济角度而言，离子液体及其衍生材料也面临着不小的挑战。

jiangnanan

2018自然科学基金面上项目-阴离子-极性配体双功能化超微孔材料的设计合成与氙/氪分离性能
批准号        21878261        学科分类        ( B080404 )
负责人        杨启炜        职称                单位名称        浙江大学
资助金额        66万元        项目类别        面上项目        起止年月        2019年01月01日 至 2022年12月31日

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