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[专家学者] 中国科学院上海有机化学研究所陈耀峰

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发表于 2017-9-28 14:17:05 | 只看该作者 回帖奖励 |倒序浏览 |阅读模式
姓 名:陈耀峰       
性 别:
职 称:研究员       
学 历:博士研究生
电 话:021-54925149       
传 真:021-64166128
电子邮件:yaofchen@mail.sioc.ac.cn       
个人主页:http://chenyaofeng.sioc.ac.cn
通讯地址:上海市零陵路345号 200032       
简历:
1970年出生于浙江省杭州市,“百人计划”研究员,课题组长; 2006年2月-中国科学院上海有机化学研究所研究员,课题组长; 2003年8月-2005年10月美国加州大学SantaBarbara分校化学系,PostdoctoralFellow; 2002年10月-2003年7月加拿大蒙特利尔大学化学系,PostdoctoralFellow; 1999年12月-2002年8月中国科学院上海有机化学研究所,博士后; 1996年9月-1999年10月浙江大学高分子系,博士,导师:沈之荃院士; 1993年9月-1996年6月杭州大学化学系,硕士,导师:龚钰秋教授; 1989年9月-1993年6月杭州师范学院化学系本科。
研究方向:
金属有机化合物,特别是新型稀土金属有机化合物的设计, 合成及催化的有机和高分子合成.
专家类别:百人;研究员;杰青
职务:课题组长
获奖及荣誉:上海市科技进步一等奖 (排名第三)
代表论著:
1.Jiaxiang Chu, Xianghao Han, Christos E. Kefalidis, Jiliang Zhou, Laurent Maron,* Xuebing Leng, Yaofeng Chen,* “Lewis Acid Triggered Reactivity of a Lewis Base Stabilized Scandium Terminal Imido Complex: C-H bond Activation, Cycloaddition, and Dehydrofluorination” J. Am. Chem. Soc. 2014, 136, 10894-10897.
2.Yingdong Lv, Christos E. Kefalidis, Jiliang Zhou, Laurent Maron,* Xuebing Leng, Yaofeng Chen,* “Versatile Reactivity of a Four-coordinate Scandium Phosphinidene Complex: Reduction, Addition and CO Activation reactions” J. Am. Chem. Soc. 2013, 135, 14784-14796.
3.Jiaxiang Chu, Christos E. Kefalidis, Laurent Maron,* Xuebing Leng, Yaofeng Chen,* “Chameleon Behavior of a Newly Synthesized Nitrilimine Scandium Derivative” J. Am. Chem. Soc. 2013, 135, 8165-8168.
4.Jiliang Zhou, Jiaxiang Chu, Yanyan Zhang, Guang Yang, Xuebing Leng, Yaofeng Chen,* “An Yttrium Hydride-Silane Complex as a Structural Model for a σ-Bond Metathesis Transition State” Angew. Chem. Int. Ed. 2013, 52, 4243-4246.
5.Xiufang Wang, Weijie Peng, Peng Cui, Xuebing Leng, Wei Xia, Yaofeng Chen,* “Synthesis and Catalytic Activity of Amido-boratabenzene Complexes of Rare-earth, Zirconium and Chromium” Organometallics, 2013, 32, 6166-6169.
6.Jiaxiang Chu, Erli, Lu, Yaofeng Chen,* Xuebing Leng, “Reversible Addition of Si-H Bond of Phenylsilane to Sc=N Bond of Scandium Terminal Imido Complex” Organometallics, 2013, 32, 1137-1140. (Invited for the special issue entitled “Recent Advances in Organo-f-Element Chemistry”).
7.Yangjian Hu, Xiufang Wang, Yaofeng Chen,* Lucia Caporaso,* Luigi Cavallo,* Eugene Y.-X. Chen,* “Rare-Earth Half-Sandwich Dialkyl and Homoleptic Trialkyl Complexes for Rapid and Stereoselective Polymerization of a Conjugated Polar Olefin” Organometallics, 2013, 32, 1459-1465.
8.Erli Lu, Yuanyuan Yuan, Yaofeng Chen,* Wei Xia, “1-Methyl Boratabenzene Yttrium Alkyl: A Highly Active Catalyst for Dehydrocoupling of Me2NH×BH3” ACS Catalysis 2013, 3, 521-524. (Invited for the virtual special issue on Catalysis at SIOC).  
9.Erli Lu, Qinghai Zhou, Yuxue Li, Jiaxiang Chu, Yaofeng Chen,* Xuebing Leng, Jie Sun, “Reactivity of Scandium Terminal Imido Complexes towards Metal Halides” Chem. Commun. 2012, 48, 3403-3405.
10.Erli Lu, Yaofeng Chen,* Jiliang Zhou, Xuebing Leng, “C−P or C−H Bond Cleavage of Phosphine Oxides Mediated by an Yttrium Hydride” Organometallics, 2012, 31, 4574-4578.
11. Yilin Sun, Guangming Wu, Dinghai Cen, Yaofeng Chen,* Limin Wang,* “Synthesis and Catalytic Activity of Heterogeneous Rare-earth Metal Catalysts Coordinated with Multitopic Schiff-base Ligands” Dalton Trans., 2012, 41, 9682-9688.
12. Jiaxiang Chu, Erli Lu, Zhixiao Liu, Yaofeng Chen,* Xuebing Leng, Haibing Song “Reactivity of a Scandium Terminal Imido Complex towards Unsaturated Substrates” Angew. Chem. Int. Ed. 2011, 50, 7677-7680.
13. Yingdong Lv, Xin Xu, Yaofeng Chen,* Xuebing Leng, Maxim V. Borzov “Well-defined Soluble P3- Containing Rare-earth Metal Compounds” Angew. Chem. Int. Ed. 2011, 50, 11227-11229.
14. Erli Lu, Jiaxiang Chu, Yaofeng Chen,* Maxim V. Borzov, Guangyu Li, “The Scandium Terminal Imido Complexes Induced C-H Bond Selenation and the Formation of Sc-Se Bond” Chem. Commun. 2011, 47, 743-745.
15. Erli Lu, Yaofeng Chen,* Xuebing Leng, “Yttrium Anilido Hydride: Synthesis, Structure, and Reactivity” Organometallics, 2011, 30, 5433-5441.
16. Yuanyuan Yuan, Xiufang Wang, Yuxue Li, Liyan Fan, Xin Xu, Yaofeng Chen,* Guangyu Li, Wei Xia, “Rapid Entry to Functionalized Boratabenzene Complexes Through Metal Induced Hydroboration at Anionic 1-H-Boratabenzene Ligand” Organometallics 2011, 30, 4330-4341.
17. Peng Cui, Yaofeng Chen,* Guangyu Li, Wei Xia, “Versatile Reactivities of ansa-Heteroborabenzene Divalent Ytterbium Amide toward Alkali-Metal Salts and the Generation of Heterometallic Ytterbium-Alkali-Metal Boratabenzene Complexes” Organometallics 2011, 30, 2012-2017.
18. Erli Lu, Wei Gan, Yaofeng Chen,* “Monoalkyl and monoanilide yttrium complexes containing tridentate pyridyl-1-azaallyl dianionic ligands” Dalton Trans. 2011, 40, 2366-2374. (Invited for the themed issue entitled “New Talent: Asia”).
19. 刘智潇, 陈耀峰,*  “稀土金属有机化学的一个前沿领域:稀土卡宾化学” 中国科学(化学), 2011, 41, 304-313. (评述)。
20. Erli Lu, Yuxue Li, Yaofeng Chen,* “A Scandium Terminal Imido Complex: Synthesis, Structure and DFT Studies” Chem. Commun., 2010, 46, 4469-4471. (封面文章)
21. Yuanyuan Yuan, Yaofeng Chen,* Guangyu Li, Wei Xia, “Synthesis and Structural Features of Boratabenzene Rare-earth Metal Alkyl Complexes” Organometallics 2010, 29, 3722-3728.
22. Xin Xu, Yaofeng Chen,* Jian Feng, Gang Zou, Jie Sun, “Half-sandwich Mono(indenyl) Rare-earth Metal Dialkyl Complexes: Syntheses, Structures and Catalytic Reactivities of  (1,3-(SiMe3)2C9H5)RE(CH2SiMe3)2(THF)” Organometallics 2010, 29, 549-553.
23. Yangjian Hu, Xin Xu, Yuetao Zhang, Yaofeng Chen,* Eugene Y.-X. Chen,* “Polymerization of Naturally Renewable Methylene Butyrolactones by Half-Sandwich Indenyl Rare Earth Metal Dialkyls with Exceptional Activity” Macromolecules 2010, 43, 9328-9336.
24. Peng Cui, Yaofeng Chen,* Maxim V. Borzov, “Neodymium(III) Phosphinidene Complexes Supported by Pentamethylcyclopentadienyl and Hydrotris(pyrazolyl)borate Ligands” Dalton Trans. 2010, 39, 6886-6890. (Invited for the themed issue entitled “New Horizons in Organo-f-element Chemistry”)
25. Xin Xu, Yaofeng Chen,* Gang Zou, * Jie Sun, “Single, Double and Triple Deprotonation of a β-Diketimine Bearing Pendant Pyridyl Group and the Corresponding Rare-earth Metal Complexes” Dalton Trans. 2010, 39, 3952-3958.
26. Peng Cui, Yaofeng Chen,* Qiang Zhang, Guangyu Li, Wei Xia, “Synthesis, and Structural Characterization of Solvent-free Divalent Ytterbium Bis(boratabenzene) and (Cyclopentadienyl)(Boratabenzene) Complexes” J. Organomet. Chem. 2010, 695, 2713-2719. (Invited for the special issue of Organ-f-element Chemistry at Pacifichem 2010)
27. Erli Lu, Wei Gan, Yaofeng Chen,* “Monoalkyllanthanide Complexes with New b-Diketiminato Derivative Dianionic Ligands” Organometallics 2009, 28, 2318.
28. Xin Xu, Yaofeng Chen,* Jie Sun, “Indenyl Abstraction vs Alkyl Abstraction of (Indenyl)ScR2(THF) by [Ph3C][B(C6F5)4]: Aspecific and Syndiospecific Styrene Polymerization” Chem. Eur. J. 2009, 15, 846-850.
29. Peng Cui, Yaofeng Chen,* Guangyu Li, Wei Xia, “An ansa-Hetero-Borabenzene Divalent Lanthanide Amide via C-H Bond Cleavage” Angew. Chem. Int. Ed. 2008, 47, 9944-9947.
30. Peng Cui, Yaofeng Chen,* Xin Xu, Jie Sun, “An Unprecedented Lanthanide Phosphinidene Halide: Synthesis, Structure and Reactivity” Chem. Commun. 2008, 5547-5549.
31. Yuanyuan Yuan, Yaofeng Chen,* Guangyu Li, Wei Xia, “Reactions of Boratabenzene Yttrium Complexes with KN(SiMe3)2: Salt Elimination and p-Ligand Displacement” Organometallics 2008, 27, 6307-6312.
32. Peng Cui, Yaofeng Chen,* Guoping Wang, Guangyu Li, Wei Xia, “Divalent Ytterbium Boratabenzene Complex (C5H5BNPh2)2Yb(THF)2: Synthesis, Structure and Solvent-Mediated Redox Transformation” Organometallics 2008, 4, 4013-4016.
33. Xin Xu, Xiaoyan Xu, Yaofeng Chen,* Jie Sun, “Dialkyl lanthanide Metal Complexes Containing New Tridentate Monoanionic Ligands with Nitrogen Donors” Organometallics 2008, 27, 758-763.
34. Peng Cui, Yaofeng Chen,* Xiaohua Zeng, Jie Sun, Guangyu Li, Wei Xia, “Boratabenzene Derivatives of Divalent Samarium: Syntheses, Structures and Catalytic Reactivities of (C5H5BXPh2)2Sm(THF)2(X = N, P)” Organometallics 2007, 26, 6519-6521.    

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发表于 2018-5-16 10:58:49 | 只看该作者
报告主题:稀土金属-主族元素双键化学
报告人:陈耀峰研究员 中国科学院上海有机化学研究所
主持人:赵晓丹教授
时间:2018年5月11日(星期五)上午10:30
地点:中山大学丰盛堂芙兰学术中心A403


报告人简介:
中科院上海有机化学研究所金属有机国家重点实验室研究员。 1999年毕业于浙江大学, 获博士学位;先后在中科院上海有机化学研究所,加拿大蒙特利尔大学和美国加州大学Santa Barbara 分校从事博士后研究工作。2006年受聘于中科院上海有机化学研究所,课题组长,博士生导师,入选中科院 “百人计划”。从事稀土金属有机配合物化学研究,2013年获得国家杰出青年基金。


近期代表性论文:
1. Lu, E. L.; Chu, J. X.; Chen, Y. F. Scandium Terminal Imido Chemistry. Acc. Chem. Res. 2018, 51, 557-566.
2. Mao, W. Q.; Xiang, L.; Chen, Y. F. Rare-earth Metal Complexes of b-Diketiminato Ligands Bearing Pendant Nitrogen or Oxygen Donors. Coord. Chem. Rev. 2017, 346, 77-90.
3. Cui, P.; Chen, Y. F. Boratabenzene Rare-earth Metal Complexes. Coord. Chem. Rev. 2016, 314, 2-13.
4. Mao, W. Q.; Xiang, L.; Maron, L.; Leng, X. B.; Chen, Y. F. Nonchelated Phosphoniomethylidene Complexes of Scandium and Lutetium. J. Am. Chem. Soc. 2017, 139, 17759-17762.
5. Mao, W. Q.; Xiang, L.; Alvarez Lamsfus, C.; Maron, L.; Leng, X. B.; Chen, Y. F. Highly Reactive Scandium Phosphinoalkylidene Complex: C-H and H-H Bonds Activation. J. Am. Chem. Soc. 2017, 139, 1081-1084.


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